Impact of Opportunity Crudes on Refinery Crude Oil Fouling – Diagnosis and Mechanism

Significance 

Generally, oil reserves denote the amount of crude oil that can be technically recovered at a feasible cost.  The output of oil wells in any given oil field irreversibly dwindle with continued extraction with time. In the US, tremendous growth in the production of tight oils and shale gas has resulted in the continued decline in the quantity of legacy Pennsylvania grade crude oil. The latter coupled by volatile crude oil prices has prompted American Refining Group (ARG) to initiate processing of a wide variety of discounted opportunity crudes in a bid to expand its crude oil feedstock slate to maintain profit margins.

Opportunity crudes are less expensive and more readily available than traditional crudes and possess various properties that may vary significantly. As opportunity crude usage increases, crude oil fouling and unexpected corrosion have become major issues in the refinery crude unit’s hot heat exchanger train (HHET) and other process units. Consequently, crude oil fouling in the refinery has resulted in increased energy consumption, reduced throughput, and more frequent shutdowns. There exist an array of studies demonstrating the effects of opportunity crudes from various geological formations, however, little information exits on the impact of opportunity crude variation in composition, blended with Pennsylvania (PA) grade paraffinic crude oil, on the crude unit (CU) hot heat exchanger train fouling.

To date, ARG has had no reported major coking or fouling issues with refinery process units while processing 100% Pennsylvania grade legacy crude oil. However, since the introduction of various opportunity crudes, a myriad of process challenges in the refinery the result in frequent crude unit turnarounds (TARs)/heat exchanger cleanouts and greater production losses. To this note, a group of researchers from the Research & Development Department, American Refining Group, Inc. in Pennsylvania: Prafulla D. Patil, Mike Kozminski, John Peterson and  Sailesh Kumar, evaluated the interpretation of crude unit hot heat exchanger train effectiveness based on opportunity crudes in the crude blend. Their work is currently published in the research journal, Industrial & Engineering Chemistry Research.

Generally, fouling at the refinery crude unit HHET resulting from the impact of Pennsylvania grade crude blended with opportunity crude oils was investigated. The researchers studied thermal and hydraulic fouling models in a bid to detect changes in the fouling behavior of the crude unit’s hot heat exchanger train. In their study, various crude oil fouling diagnostic tools were used to determine the root causes of fouling including foulant chemical characterization, crude oil compatibility, caustic injection evaluation, crude furnace operation, crude corrosion, and in-house developed fouling indices.

The authors reported that the percentage effectiveness of the crude unit heat exchanger train decreased significantly with the introduction of Utica and Michigan crudes at higher rates. Moreover, at controlled optimized rates in the crude blend, Ontario and New Mexico crudes showed a positive influence on the crude oil fouling rate reduction trend. With the exception of the substandard Kentucky crude which revealed high Insolubility number (IN =8), the oil compatibility model (OCM) indicated that all other tested crudes had an insolubility number of “0”, which inferred that they were all compatible with Pennsylvania grade crude in all proportions

In summary, the impact of opportunity crudes (Utica, Michigan, Kentucky, Ontario, New Mexico) blended with Pennsylvania (PA) grade legacy crude oil on the refinery crude unit hot heat exchanger train (HHET) fouling was evaluated. The primary fouling factors investigated at the crude unit hot exchanger train were filterable solids/Inorganics present in the opportunity crudes, crude oil incompatibility, velocity driven deposits and thermal degradation. Thermal cracking was detected as the primary cause of the coking issue in the crude tower boot section due to high severity heater and column operation. In an interview with Advances in Engineering, Prafulla Patil highlighted that the simultaneous monitoring of the thermal and hydraulic performance of refinery heat exchangers was crucial to detect the fouling behavior with changing crude oil composition. The research work would be helpful to refinery professionals who are engaged in crude oil evaluation to expand its crude oil feedstock slate for better utilization of refinery assets and maintain profit margins in this volatile crude oil market.

Impact of Opportunity Crudes on Refinery Crude Oil Fouling – Diagnosis and Mechanism - Advances in Engineering

About the author

Dr. Prafulla D. Patil is Research & Development Engineer at American Refining Group, Bradford, PA. He received his PhD in Chemical Engineering from New Mexico State University (NMSU), Las Cruces, USA, in 2010 and did Postdoctoral Research Associate at NMSU. Prafulla is a Senior Member of American Institute of Chemical Engineers (AICHE). He has development and commercialization experience with petroleum refining technology and pilot plant proficiency in advanced biofuel production. Dr. Patil has published over 30 research articles in international peer-reviewed journals, symposia, book chapters, and invited international conferences (Citations 2500+). Prafulla holds U.S. patents on algal biofuel conversion technologies.

About the author

Michael J. Kozminski is the Director of R&D at American Refining Group, Bradford, PA. He received his B.S. in Chemistry from the University of Pittsburgh @ Bradford in 1991. Michael has worked in the petroleum refining industry for over 28 years and has held various technical roles. Michael joined American Refining Group in 2007 as the Manager of R&D. Prior to joining American Refining Group, Michael was the R&D/Quality Manager for International Waxes in Smethport, PA.

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About the author

John Peterson is the Principal Chemist of R&D at American Refining Group, Bradford, PA. He received his Bachelor’s degree in chemistry from University of Pittsburgh, Bradford, PA in 1999 and Master’s degree in analytical chemistry from the Illinois Institute of Technology in 2015. John has been with American Refining Group since 1994 and has held various technical roles. John is a veteran of the United States Army.

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About the author

Dr. Sailesh Kumar is a Director of R&D at American Refining Group, Bradford, PA. He received his B.S. in Mechanical Engineering from IIT Roorkee, India, and a Ph.D. from the Chemical Reaction Engineering Laboratory at Washington University in St. Louis. Prior to joining American Refining Group in 2019, he was with UOP-Honeywell for 23 years holding various technical roles related to Process Modeling and Hydroprocessing.

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Reference

Prafulla D. Patil, Mike Kozminski, John Peterson, and Sailesh Kumar. Fouling Diagnosis of Pennsylvania Grade Crude Blended with Opportunity Crude Oils in a Refinery Crude Unit’s Hot Heat Exchanger Train. Industrial & Engineering Chemistry Research 2019, volume 5838, page 17918-17927.

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