Superwettability-based separation

From oil/water separation to polymer/water separation and bubble/water separation

Significance 

The separation of mixtures is of significant value in both research and industrial applications. Separation processes convert the mixture or solution of different chemical substances into individual constituents forming the mixture. To date, many separation techniques have been developed to achieve various separation functions. For example, the superwettability-based process has been widely used to separate oil/water mixtures due to their different wetting behaviors. Unfortunately, this approach is more appropriate for simple oil/water separation and less effective for separating underwater bubbles and mixtures of liquid polymers and water. Therefore, considering the rapid technological advancement and growing application of polymer materials, developing effective and efficient polymer/water and bubble/water separation strategies is highly desirable.

Research has revealed that water/oil mixtures can be efficiently separated by porous materials with either underwater superoleophobicity or superhydrophobicity properties. Previously, superwetting states related to underwater polymers and bubbles were developed. They include underwater superpolymphobicity and superaerophobicity that function in a manner similar to the oil repellence of the underwater superoleophobic surfaces in that the superpolymphobic and superaerophobic materials repel the liquid polymers and bubbles, respectively. This is an indication that superwetting materials can potentially be applied to separate liquid polymers and tiny bubbles from water even though this area has remained largely underexplored.

In a recent study by Xi’an Jiatong University scientists at School of Electronic Science and Engineering: Professor Jiale Yong, Professor Qing Yang, Dr. Jinglan Huo, Professor Xun Hou, and Professor Feng Chen used the wettability-based oil/water separation strategy to separate the mixtures of liquid polymers and water as well as that of bubbles and water. The aim was to extend the scope of applications of the well-developed wettability separation method. Their research work is currently published in the journal, Nano Select.

In their approach, the authors relied on the special surface wettability properties of the separation materials to achieve the expected results. The micro/nanostructures were produced on a stainless-steel mesh via femtosecond laser treatment to endow the mesh with desirable properties. The feasibility of separating the liquid polymers and bubbles from water using the as-prepared superwetting mesh was experimentally verified.

The results showed that the superwetting mesh exhibited underwater superoleophobicity, superpolymphobicity and superaerophobicity properties attributed to the formation of the laser-induced microstructures. For instance, a CA of 154.8°, 156.3°, and 153.7° was recorded for the small oil droplet, polymer droplet, and bubble on the structured mesh in water, respectively. As such, the resulting mesh exhibited strong repellence to oils, liquid polymers, and bubbles in the water medium. Moreover, water penetrated the structured mesh due to the superhydrophilicity while oils, bubbles, and liquid polymers got intercepted due to their repellence of the laser-induced microstructures. This phenomenon allowed the successful separation of oils, liquid polymers, and bubbles from the water with a high separation efficiency. In addition, it was worth noting that the presented separation method based on superwettability demonstrated potential application in separating various liquid-gas and liquid-liquid mixtures.

In a nutshell, the study reported an extension of superwettability-based oil/water separation method to separate polymer/water and bubble/water mixtures. The resulting laser-treated mesh exhibited remarkable superoleophobicity, superpolymphobic and superaerophobic properties desirable to achieve the various separation processes. By taking advantage of the different wetting behaviors of the mesh to oils, polymers, and bubbles, the presented method successfully separated the oils, liquid polymer, and bubble from the water with a high separation efficiency. Apart from separating oil, polymers and bubbles from water, the as-prepared superwetting mesh also demonstrated potential applications in separating various liquid/liquid and liquid/gas mixtures. Altogether, first author, Professor Jiale Yong in a statement to Advances in Engineering, pointed out that the diversified wettability-based separation process is a promising separation method for numerous applications, including energy utilization, environmental protection, and industrial manufacturing.

Superwettability-based separation: From oil/water separation to polymer/water separation and bubble/water separation - Advances in Engineering

About the author

Prof. Jiale Yong is currently an associate professor at the School of Electronic Science and Engineering at Xi’an Jiaotong University. He received his BS degree from Xi’an Jiaotong University in 2011. After that, he joined Prof. Chen’s research group and received a Ph.D. in Electronic Science and Technology from Xi’an Jiaotong University in 2016. Then, he started to work at Xi’an Jiaotong University. His research interests include femtosecond laser microfabrication, controlling wettability of solid surfaces, and bioinspired designing superhydrophobic and superoleophobic interfaces.

About the author

Prof. Feng Chen is a professor at the School of Electronic Science and Engineering Engineering at Xi’an Jiaotong University, where he directs the Femtosecond Laser Laboratory. He received a BS degree in physics from Sichuan University, China, in 1991, and then began to work for the Chinese Academy of Science (1991 to 2002), where he was promoted to a full professor in 1999. He received a Ph.D. in Optics from the Chinese Academy of Science in 1997. In 2002, he joined Xi’an Jiaotong University, where he became a group leader. His current research interests are femtosecond laser microfabrication and bionic microfabrication.

Reference

Yong, J., Yang, Q., Huo, J., Hou, X., & Chen, F. (2021). Superwettability‐based separation: From oil/water separation to polymer/water separation and bubble/water separationNano Select, 1-9.

Go To Nano Select

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