Ultra-Low-Concentration Metal-GNP Nanofluids for Enhanced Boiling Heat Transfer

Significance 

With the ever-growing demand for efficient heat dissipation in high heat flux electronics and energy systems, conventional working medium are rapidly approaching their thermal performance limits. Developing scalable, low-concentration nanofluid solutions for enhanced boiling heat transfer has thus become a critical research priority. In response to this challenge, the present study introduces and investigates a novel class of metal-functionalized graphene nanoplatelet (GNP) nanofluids. By integrating experimental boiling measurements with theoretical modeling, the work reveals both the enhancement mechanisms and engineering potential of these advanced working media.

The research team synthesized ultra-low-concentration nanofluids (0.001–0.003 wt%) using copper (Cu) and iron (Fe) functionalized GNPs, and systematically evaluated their boiling characteristics. The results show that GNP-Cu nanofluids, at only 0.003 wt%, achieve a critical heat flux (CHF) of 1900.7 kW/m² and a heat transfer coefficient (HTC) of 96.3 kW/(m²·K). These values represent increases of 75.1% and 80.4%, respectively, over deionized water, marking one of the most significant enhancements reported to date at such low concentrations. This demonstrates the highly efficient utilization of nanomaterial properties without the need for large particle loadings.

To facilitate practical application, the study further develops a modified boiling curve model based on the classical Rohsenow correlation. By introducing correction factors tied to nanoparticle type and concentration, a linearized formulation is proposed that accurately predicts boiling behavior across GNP-Cu, GNP-Fe, and GNP-Ag nanofluids. The resulting model is compact, tunable, and generalizable—making it a valuable tool for rapid thermal system assessment and design.

Microscale bubble dynamics were investigated using high-speed visualization. Compared to unmodified GNP nanofluids, GNP-Cu nanofluids displayed higher nucleation site density, smaller bubble departure diameters, and shorter detachment cycles. These features effectively delayed the onset of film boiling and improved local heat transfer. The study also proposes a novel mechanism termed “nanobubble–radiation synergy,” where the high infrared emissivity of graphene leads to localized vapor layer formation, enhancing microscale agitation and vaporization processes. Though not directly validated, this hypothesis offers a forward-looking direction for nanofluid research involving optical or radiative effects.

In summary, this study presents an integrated advance in nanofluid design, performance measurement, mechanistic understanding, and predictive modeling. It convincingly demonstrates that significant boiling heat transfer enhancement can be achieved through metal-functionalized GNPs at low concentrations, avoiding the need for high loading or rare materials. The results provide a solid theoretical and experimental foundation for deploying these working media in next-generation thermal management systems for electronics, power devices, and renewable energy platforms.

Ultra-Low-Concentration Metal-GNP Nanofluids for Enhanced Boiling Heat Transfer - Advances in Engineering

About the author

Yindong Song, Ph.D., is an Associate Professor at Jiangsu University of Science and Technology.
His research focuses on functionalized graphene nanofluids and boiling heat transfer enhancement on biphilic surfaces. He is also involved in engineering studies on pollutant collection in large-scale 3D industrial workshops, automated spray coating for ships and heavy equipment, and integrated pollutant control technologies. He has published more than 10 peer-reviewed journal articles and holds 13 invention patents.
Email: [email protected]

About the author

Linfeng Xiang is currently a Ph.D. candidate in Power Engineering and Engineering Thermophysics at Xi’an Jiaotong University. He received his bachelor’s and master’s degrees from Jiangsu University of Science and Technology, where he conducted research under the supervision of Associate Professor Yindong Song. His research focuses on the synthesis of metal-functionalized graphene, formulation of nanofluids, experimental system development, and SEM characterization of deposition surfaces.

About the author

Kambiz Vafai

Distinguished Professor
Director, Masters of Science in Engineering (MSOL)
University of California, Riverside

Kambiz Vafai is an internationally leading figure in the fields of heat and mass transfer and fluid mechanics who is the Distinguished Professor at UCR where he started as a Presidential Chair. He received his B.S. degree in Mechanical Engineering from the University of Minnesota, Minneapolis and M.S. and Ph.D. degrees from the University of California, Berkeley. Dr. Vafai is a Fellow of the American Society of Mechanical Engineers (ASME, since 1992), Fellow of American Association for Advancement of Science (AAAS, since 2002), Fellow of World Innovation Foundation (since 2003) and Associate Fellow of American Institute of Aeronautics and Astronautics (AIAA, since 1998), and he has been a member or the chair of numerous ASME and AIAA National committees. He is currently the Director of Online Master-of-Science Program in Engineering at UCR. There have been tens of thousands of Google scholar and ISI citations of Dr. Vafai’s articles.  While he was at Ohio State University, he won the outstanding research awards as assistant, associate and full professor categories.  Dr. Vafai was the recipient of the prestigious ASME Classic Paper Award in 1999 and he had received the 2006 ASME Memorial Award, given to him “for Outstanding Contributions to and Leadership in Research on Convection in Porous Media, Convection in Enclosed Fluids, and Flat-Shaped Heat Pipes.” He was given the International Society of Porous Media (InterPore) Highest Award (2011) “In Recognition of Outstanding & Extraordinary Contributions to Porous Media Science, The International Society of Porous Media has Elected Kambiz Vafai an Honorary Lifetime Member”. He was also the recipient of the 75th Anniversary Medal of ASME Heat Transfer Division. There is an Honorable Introduction of the VAFAI number in Physics of Fluids. He holds 17 US patents associated with electronic cooling, medical applications and detection.

Reference

Xiang, L., Song, Y., Yang, D., Zhang, Z., Cui, Y., & Vafai, K. (2023). Experiments and modeling of boiling heat transfer of GNP nanofluids with metallic elements. Experimental Heat Transfer, 38(2), 127–144. https://doi.org/10.1080/08916152.2023.2298495

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