Fabrication of Patterned Concave Microstructures by Inkjet Imprinting

Significance Statement

  

Inkjet printing technique has been extensively used for the deposition of functional materials. It can also serve as an etching technique to fabricate surface patterns by printing etching inks onto soluble polymer substrates. However, inherent transverse ink diffusion leads to low feature resolution for the inkjet etching technique.

Scientists from the Key Laboratory of Green Printing at Institute of Chemistry, Chinese Academy of Sciences developed an inkjet imprinting technique to fabricate microstructures with high resolution by combing the inkjet printing technique with imprinting lithography. By using ink droplets as templates, they facilely fabricated concave microstructures, such as microwells and microgrooves on polydimethylsiloxane (PDMS) surfaces in a highly controllable manner. This low-cost microfabricating strategy could be anticipated to find numerous applications in the large-scale fabrication of microfluidic chips, biochips and various functional devices. 

About The Author

Dr. Bin Bao was born in 1987. He received his B.Sc. degree in applied chemistry from Beihang University in 2010. Then he joined Prof. Yanlin Song’s group at Institute of Chemistry, Chinese Academy of Sciences (ICCAS).He received his Ph.D. degree in physical chemistry from ICCAS in 2015. His current scientific interests are focused on the fabrication and patterning of functinal and structural materials by inkjet printing technologies, and the fabrication of bio-inspired materials with special wettability. 

 

About The Author

Prof. Yanlin Song was born in 1969. He received his Ph.D. degree from the Department of Chemistry at Peking University in 1996. Then he conducted research as a postdoctoral follow in the Department of Chemistry of Tsinghua University from 1996 to 1998. He has been working at Institute of Chemistry Chinese Academy of Sciences (ICCAS) since 1998. His research interests include information function materials, application of polymers photonic crystals, green-printing materials and technology. He has published more than 230 academic papers in scientific journals, 1 book and 8 chapters, and has been granted more than 50 patents. He won the First Prize of Beijing Science and Technology Award in 2004, the Second Prize of National Natural Science Award in 2005 and 2008, the National Science Fund for Distinguished Young Scholars in 2006, the Prestigious Chinese Chemical Society-Akzo Nobel Chemistry Award in 2010, The Outstanding Youth Award of Chinese Academy of Sciences in 2010, and the Outstanding Youth Achievement Award of China Association for Science and Technology in 2011, etc.. 

 

Journal Reference

Advanced Functional Materials, Volume 25, Issue 22, pages 3286–3294, 2015.

Bin Bao1,2, Jieke Jiang1,2, Fengyu Li1,Pengchao Zhang1,2, Shuoran Chen1,2,Qiang Yang1,2, Shutao Wang1, Bin Su1,Lei Jiang1 , Yanlin Song1,* 

Show Affiliations
  1. Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Green Printing, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
  1. School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, P. R. China
 

Abstract

Concave microstructures such as microwells and microgrooves are widely utilized in fields such as biochips, microfluidics, and functional devices. Previously, concave microstructure fabrication was mostly based on laser etching or lithography which is either costly or of multisteps. The inkjet etching method is a direct structuring technique, but limited by its inherent transverse ink diffusion that leads to low feature resolution. Nanoimprint lithography can reach submicro and even nano ranges, whereas an elaborate template is needed. Thus, it is still a challenge to realize controllable fabrication of concave microstructures in large areas with high efficiency and resolution. Here, a template-free strategy to fabricate concave microstructures with high resolution by inkjet imprinting is provided. In this method, a sacrificial ink is inkjet-printed onto a precured viscoelastic surface and imprints its shapes to construct concave microstructures. The morphology of the microstructures could be adjusted by controlling the interaction between the two immiscible phases. The microwells/microgrooves could be used to pattern single cells and functional materials such as optical, electronic, and magnetic nanoparticles. These results will open a new pathway to fabricate concave microstructures and broaden their applications in various functional devices.

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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Figure Legend: Sacrificial polyacrylic acid (PAA) solution ink is inkjet-printed onto pre-cured PDMS surfaces. Microdots or microwires are constructed depending on the printed ink drop distances. The microdots and microwires imprint their shapes onto the pre-cured PDMS surfaces, and these shapes can be kept by completely solidifying the underlying surfaces. Finally, microwells and microgrooves are constructed on the surfaces by rinsing away the sacrificial PAA ink.

FABRICATION PATTERNED CONCAVE MICROSTRUCTURES INKJET IMPRINTING