High Infrared Emissivity Ceramic Coatings for Metallic Thermal Protection Systems


High infrared emissivity ceramic coatings for protection of metallic thermal protection systems (TPS) are urgently needed in reusable launch vehicles (RLVs). The basic technical requirements for the coating to protect metallic TPS include a spectral emissivity of higher than 0.8 over a broad waveband to maximize re-radiation and good high temperature protection against oxidation of the underlying metallic substrate. However, how to fabricate a high emissivity coating with desirable properties of high adhesion, lightweight, low cost, and easy repairing still remains a serious challenge.

A team of researchers led by Prof. Yaming Wang and Prof. Jiahu Ouyang from Harbin Institute of Technology in China, developed a variety of high emissivity ceramic coatings on metallic surfaces such as TiAl[1], Ti[2], Nb[3] et al by microarc oxidation (MAO) method for thermal protection. Moreover, to further improve the thermal emission of ceramic coatings, a new MAO coating incorporated with SiC particles was developed for the first time on Ti2AlNb alloy in a Na2SiO3 basic electrolyte. The chemical composition, microstructure and emissivity enhancement mechanisms of MAO ceramic coatings incorporated with or without SiC particles were investigated. Their work was recently published in peer-reviewed journal, Applied Surface Science.

In their work, high emissivity ceramic coatings incorporated with SiC have been successfully formed on Ti2AlNb alloy by microarc oxidation. These ceramic coatings are composed of R-TiO2, A-TiO2, Al2SiO5 and SiC phase as well as amorphous phase. The introduction of SiC into the Na2SiO3 electrolyte leads to a significant change of coating microstructure. In addition, the addition of SiC particles reduces the volume of clusters structure and the diameter of micropores, however, increases obviously the number of micro-pores in ceramic coating.

Yaming Wang and his colleagues demonstrated that MAO ceramic coatings improve infrared radiation properties of Ti2AlNb alloy at high temperature. The coating incorporated with 10g/L SiC particles exhibits excellent infrared emissivity property at 600 oC, which has the emissivity of more than 0.80 over the whole waveband of 3-20 μm. Furthermore, they elaborated the emissivity enhancement mechanisms. The SiC particles distributed in the oxide matrix influences the phase constituents and surface morphologies, and finally enhances the infrared emissivity of the coating.

In addition, the team also develops a variety of high emissivity coatings on Al [4] and Mg [5] alloy radiators for enhanced radiating heat dissipation of high power devices. Generally, the MAO technique is a universal and efficient method by tailoring the electrical parameters and electrolyte compositions to enhance the thermal protection of metallic TPS and high efficient thermal dissipation of power devices.


High Infrared Emissivity Ceramic Coatings for Metallic Thermal Protection Systems. Advances in Engineering
The normal spectral emissivity of MAO ceramic coatings incorporated with SiC


High Infrared Emissivity Ceramic Coatings for Metallic Thermal Protection Systems. Advances in Engineering
Surface and cross-section morphologies of MAO coatings incorporated with SiC


About the author

Yaming Wang is a professor in Materials Science and vice leader at Institute for Advanced Ceramics (IAC), Harbin Institute of Technology (HIT). He got his Master degree and PhD from HIT in 2001 and 2006, respectively. Then he has a position as a lecture in HIT, and shortly got the Award of New Century Excellent Talents in the Ministry of Education due to his good academic achievements in 2008. He went to Manchester University for one-year visiting research supported from the China Scholarship Council in 2012.

He holds 13 patents and a book chapter entitled “Plasma electrolytic oxidation of aluminium and titanium alloys”. He has authored or coauthored more than 100 papers in refereed journals, with SCI indexed citation of >2000 and H index of 28. He was conferred the Second prize in Natural Science Award of Heilongjiang Province in 2011. He is now focusing on elevated temperature thermal protective ceramic coatings, bioceramic coatings and new energy ceramics.

About the author

Jia-Hu Ouyang is a full professor of materials science, Harbin Institute of Technology (HIT). He received his BS (1988) from Wuhan University of Technology, MS (1991) and PhD (1994) in materials science from HIT, China. He joined the faculty of Materials Science and Engineering at HIT in 1994. He was the recipient of an Alexander von Humboldt (AvH) research fellowship at Fraunhofer Institute for Material and Beam Technology (IWS), Germany. He worked as a senior researcher at National Institute of Advanced Industrial Science and Technology (AIST), Japan, for three and a half years, and Southern Methodist University (SMU), USA, for another two years. His current research interests include advanced ceramics and composites, advanced surface engineering, tribomaterials, and rare-earth energy materials. He has authored or coauthored more than 230 peer-reviewed journal papers. For more information, please see his homepage http://homepage.hit.edu.cn/pages/ouyangjiahu.

About the author

Zhan-Guo Liu received his BS degree from Harbin Institute of Technology (HIT) in 2003. In 2008 he earned his PhD in Materials Science from HIT. Now he is an associate professor in Materials Science at the Institute for Advanced Ceramics, HIT. He worked as an academic visitor at the University of Manchester for one year funded by the China Scholarship Council in 2014. He has authored/co-authored more than 110 papers in international refereed journals. His current research interests focus on the preparation and characterization of advanced ceramics and energy materials.


[1] Yuan-Hong Wang, Zhan-Guo Liu, Jia-Hu Ouyang, Ya-Ming Wang, Yu-Jin Wang. Dependence of the infrared emissivity on SiC content and microstructure of microarc oxidation ceramic coatings formed in Na2SiO3 electrolyte. Applied Surface Science, volume 431 (2018) pages 17-23.


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[2] Z.W. Wang, Y.M. Wang, Y. Liu, J.L. Xu, L.X. Guo, Y. Zhou, J.H. Ouyang, J.M. Dai. Microstructure and infrared emissivity property of coating containing TiO2 formed on titanium alloy by microarc oxidation. Current Applied Physics, volume 11 (2011) pages 1405-1409.

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[3] Yulin Ge, Yaming Wang, Junchen Chen, Yongchun Zou, Lixin Guo, Jiahu Ouyang, Dechang Jia, Yu Zhou. An Nb2O5-SiO2-Al2O3/NbSi2/Nb5Si3 multilayer coating on Nb-Hf alloy to improve oxidation resistance. Journal of Alloys and Compounds, volume 745 (2018) pages 271-281.

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[4] Y.M. Wang, H. Tian, X. E. Shen, L. Wen, J.H. Ouyang, Y. Zhou, D.C. Jia, L.X. Guo. An elevated temperature infrared emissivity ceramic coating formed on 2024 aluminium alloy by microarc oxidation. Ceramics international, volume 39 (2013) pages 2869–2875.

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[5] Y.M. Wang, Y.C. Zou, H. Tian, L.X. Guo, J.H. Ouyang, D.C. Jia, Y. Zhou. Microarc oxidation coated magnesium alloy radiator for light emitting diode: Microstructure, thermal radiative and dissipating property. Surface and Coatings Technology, volume 294 (2016) pages 102-108.


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