Energy efficient one-pot synthesis of durable superhydrophobic coating through nylon micro-rods

Applied Surface Science, ,Volume 295,  2014, Pages 203–206.

T. Simovich, A.H. Wu, R.N. Lamb.

Surface Science and Technology Group, School of Chemistry, The University of Melbourne, Victoria 3010, Australia.

 

Abstract

A durable and superhydrophobic coating was fabricated at room temperature through encapsulating nylon micro-rods in a hydrophobic silica shell. This was achieved through the precipitation of miniemulsified nylon under high shear to generate micro-rods with high aspect ratio in the presence of methyltrimethoxysilane. The resultant coating structure resembles a network of highly entangled micro-rods that give rise to both surface roughness and hydrophobicity, resulting in contact angles greater than 155°. The embedded nylon polymer within the micro-rods imparts significant mechanical durability to the surface, resulting in a coating hardness of 2H using the pencil hardness test.

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