Exciton quenching by diffusion of 2,3,5,6-tetrafluoro-7,7’,8,8’-tetra cyano quino dimethane and its consequences on joule heating and lifetime of organic light-emitting diodes

Optics Letters, Vol. 38, Issue 19, pp. 3854-3857 (2013).

Priyanka Tyagi, Arunandan Kumar, Lalat Indu Giri, Manas Kumar Dalai, Suneet Tuli, M. N. Kamalasanan, and Ritu Srivastava.

 

CSIR-Network of Institute for Solar Energy (NISE), Physics of Energy Harvesting Division, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Road, New Delhi 110012, India and

Center for Applied Research in Electronics, Indian Institute of Technology Delhi, New Delhi 110016, India and

Laboratoire Interdisciplinaire Carnot de Bourgogne, CNRS UMR 5209, Université de Bourgogne, 9 Avenue Alain Savary, Dijon, France.

 

Abstract

 

In this Letter, the effect of F4-TCNQ insertion at the anode/hole transport layer (HTL) interface was studied on joule heating and the lifetime of organic light-emitting diodes (OLEDs). Joule heating was found to reduce significantly (pixel temperature decrease by about 10 K at a current density of 40  mA/cm2) by this insertion. However, the lifetime was found to reduce significantly with a 1 nm thick F4-TCNQ layer, and it improved by increasing the thickness of this layer. Thermal diffusion of F4-TCNQ into HTL leads to F4-TCNQ ionization by charge transfer, and drift of these molecules into the emissive layer caused faster degradation of the OLEDs. This drift was found to reduce with an increase in the thickness of F4-TCNQ.

© 2013 Optical Society of America

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