Microfluidic Synthesis of Palladium Nanocrystals Assisted by Supercritical CO2: Tailored Surface Properties for Applications in Boron Chemistry

Angewandte Chemie International Edition, Volume 51, Issue 34, pages 8525–8528, August 20, 2012.

Dr. Thomas Gendrineau,Dr. Samuel Marre, Dr. Michel Vaultier, Dr. Mathieu Pucheault, Dr. Cyril Aymonier.

 

CNRS, Université de Bordeaux, ICMCB, 87 avenue du Dr. Albert Schweitzer, 33608 Pessac (France) and

 

ISM, UMR CNRS 5255, Université Bordeaux 1, 351 Cours de la Libération, 33405 Talence (France).

 

Abstract

On the surface: A library of organic–inorganic hybrid palladium nanocrystals was synthesized using continuous supercritical microfluidic technology. The nanocatalysts show moderate to excellent activities towards CArB and CArCAr bond-forming reactions, thus illustrating the relationship between surface properties and modulated catalytic activity.

Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

 

 

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