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Angew Chem Int Ed Engl. 2012 Oct 15;51(42):10528-31.
Garai S, Haupt ET, Bogge H, Merca A, Muller A.
Fakultat fur Chemie, Universitat Bielefeld, Postfach 100131, 33501 Bielefeld, Germany.
Abstract
30 receptors in waiting position: In the porous (pentagon)(12)(linker)(30)-type molybdenum oxide capsule (see picture), the 30 positively charged linkers (five unsaturated shown for illustration in green, the others contain CO(3)(2-) ligands) can act as receptors for neutral and negatively charged ligands. Bubbling CO(2) into the solution containing the acetate-type capsules leads to the upload of CO(2) based on 30 coordinated CO(3)(2-) ligands.
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