Powerful connection of laccase and carbon nanotubes: Material for mediator-free electron transport on the enzymatic cathode of the biobattery

Electrochemistry Communications, Volume 14, Issue 1, January 2012, Pages 67-70
Ewa Nazaruk, Maciej Karaskiewicz, Kamila Zelechowska, Jan F. Biernat, Jerzy Rogalski, Renata Bilewicz

University of Warsaw, Faculty of Chemistry, Pasteura 1, 02-093 Warsaw, Poland

Gdansk University of Technology, Faculty of Applied Physics and Mathematics, Narutowicza 11/12, 80-233 Gdansk, Poland

Gdansk University of Technology, Faculty of Chemistry, Narutowicza 11/12, 80-233 Gdansk, Poland

Maria Curie Sklodowska University, Faculty of Biology and Biotechnology, Akademicka 19 Str., Lublin 20-031, Poland

Abstract

We describe the preparation of laccase/single-walled carbon nanotube bioconjugates, their application for the modification of electrodes and application of the electrodes as cathodes for the catalytic reduction of oxygen in a hybrid biofuel cell with Zn anode. Carbon nanotubes functionalized with aminoethyl residues, activated and reacted with laccase show high bioelectrocatalytic activity and are promising for the biofuel cell applications. The power density of the cell was 1 mW cm− 2 at working voltage of 0.8 V. The open circuit voltage of this hybrid cell was as high as 1.5 V.

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