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Helvetica Chimica Acta, Volume 96, Issue 6, pages 1093–1102, 2013.
Naofumi Tsukada, Tsubasa Abe, Yoshio Inoue.
Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan, and
Present address: Department of Chemistry, Faculty of Science, Shizuoka University, Shizuoka 422-8529, Japan.
Abstract
The SuzukiMiyaura coupling reaction catalyzed by dinuclear palladium complexes gave cine-substitution products along with ordinaryipso-substitution products. In the reaction in (D6)benzene, the ipso position of the cine-substitution product was highly deuterated. The H/D exchange also occurred in various positions of benzene rings.
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